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"Quinone" is the family name of dioxo derivatives of dihydroaromatic rings. Quinone with naphthalene ring is called "Naphthoquinone" , There are two types of naphthoquinone based on positions of carbonyl function,
One is -Naphthoquinone as para -quinone and the other is -Naphthoquinone as ortho -quinone. |
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-Naphthoquinone
1,4-Naphthoquinone |
-Naphthoquinone
1,2-Naphthoquinone |
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Quinones manufactured industrially in large quantities are following 3 types, Benzoquinone, Naphthoquinone and Anthraquinone. |
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| 1,4-Benzoquinone |
1,4-Naphthoquinone |
9,10-Anthraquinone |
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1,4-Naphthoquinone is an unique chemical and is manufactured by Kawasaki Kasei. 1,4-Naphthoquinone is produced by catalytic air oxidation of naphthalene with vanadium catalyst. |
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Oxidation / reduction potential of 1,4-Naphthoquinone (vs N.H.E.) is between Benzoquinone and Anthraquinone as the following, Therefore 1,4-Naphthoquinone has interesting physical properties and reactivity compared to the other two quinones. |
Series of Vitamin Ks are naturally existing 1,4-Naphthoquinone derivatives.
1,4-Naphthoquinone is industrially used as a raw material for biologically |
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| Vitamin K 1 |
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| Vitamin K 2 |
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| Vitamin K 3 |
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active substances (pharmaceuticals, agrochemicals, cosmetics, etc) and functional chemicals (desulfurization catalyst, photochemicals, etc). In addition, 1,4-naphthoquinone itself is used as polymerization inhibitor and scale inhibitor. |
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